Webb wasn't in the Senate at the time. Originally Posted by Ex-CEOYou are correct, Jim Webb was not elected to the U.S. Senate until 2006.
During his Senate campaign Webb was often critical of Shrubya. Shortly after he was elected, the following exchange occurred between the President and the Senator elect.
From Wiki:
On November 28, 2006, at a White House reception for those newly elected to Congress, Webb did not choose to wait in the line to have his picture taken with the president, whom Webb often criticized during the campaign. The president approached Webb later and asked him, "How's your boy?", referring to Webb's son, a Marine serving in Iraq. Webb replied "I'd like to get them out of Iraq, Mr. President." Bush responded, "That's not what I asked you. How's your boy?" Webb responded, "That's between me and my boy, Mr. President." The Hill cited an anonymous source who claimed that Webb was so angered by the exchange that he confessed he was tempted to "slug" the president. Webb later remarked in an interview, "I'm not particularly interested in having a picture of me and George W. Bush on my wall."
http://en.m.wikipedia.org/wiki/Jim_Webb